Einstein and the Quantum

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Einstein and the Quantum Page 38

by Stone, A. Douglas


  Friction, 190

  Fundamental constants, 116–117

  Fusion theory of light, 137–138, 281

  Galileo Galilei, 29, 89

  Games of chance, 232–234

  Gas(es): Boltzmann’s constant and, 51–55; Boyle’s Law and, 38, 221; ideal gas law, 221, 230–238, 261; interaction with radiation, 189–190; molecular motion, 39–41, 51–55; particles, 81, 96; photon gas, 221–223, 230; pressure, 38; quantum ideal, 229, 230–232, 235–238. See also Energy

  Geiger, Hans, 211, 283–284; experiment on atomic nucleus, 172; experiment with Bothe on Compton Effect, 283; experiment on elementary charge, 114, 138;

  General theory of relativity, 84, 123, 161, 183, 207; Einstein’s struggle with, 283; equivalence principle and, 123; expedition to test, 204; reaction to, 162, 205. See also Theory of relativity

  German Physical Society, 5, 8, 10–11, 12–13, 179, 201

  Ghost fields, 198–199, 276

  Gibbs, Josiah Willard, 49–50, 51, 56, 91, 95, 259

  Gladstone, William, 31

  Gordon, Walter, 273

  Gravitational attraction, 232

  Gravitational constant, 154

  Gravity, 28–29, 30, 160

  Grossman, Marcel, 20, 21–22, 45

  Ground state, 185–186, 229

  Haber, Clara, 169, 209

  Haber, Fritz, 145, 163–164, 165; World War I and, 168, 169

  Habicht, Conrad, 63–67, 84

  Harmonic oscillation, 199–200, 270

  Hartog, P. J., 218

  Hasenohrl, Fritz, 259

  Health of Einstein, 193–196

  Heat: entropy, 42, 51–55; laws of thermodynamics and, 9–10, 41; Planck’s work on light and, 5, 6–7; specific, 97, 103–110, 141, 146–147

  Heisenberg, Werner, 212, 226, 238, 255, 268–269, 284; Bohr and, 268, 269–270; Born on, 269; discovery of uncertainty principle, 278; on light absorption, 270–271; matrix mechanics of, 272–274; nomination for Nobel prize, 280; on transition frequencies, 270–271

  Hertz, Heinrich, 77–78, 83

  Herzog, Albin, 15

  Hevesy, George, 146, 179

  Higgs boson, 217

  Hilbert, David, 158–159

  Hurwitz, Adolf, 19, 166

  Ideal gas law, 221, 229–230; Einstein on, 230–238; Schrödinger and, 261–263

  Intelligent design, 42–43

  Japan, Einstein’s visit to, 212–213

  Jaumann, Gustav, 151

  Jeans, James Hopwood, 10–11, 99–102, 126–127, 131, 292; Dynamical Theory of Gases, 99; Solvay and, 149

  Jewish identity of Einstein, 208–209

  Jordan, Pascual, 192, 255, 271, 272

  Kallmann, Hartmut, 273

  Kamerlingh-Onnes, Maryke, 195

  Kelvin, Lord, 76–77, 95, 171

  Kirchoff, Gustav, 25

  Kirchoff’s law, 291

  Kleiner, Alfred, 46–47, 124

  Kurlbaum, Ferdinand, 5, 8, 11–12, 58, 99, 143

  Langevin, Paul, 157, 225, 241–242, 249–250

  Langmuir, Irving, 143–144

  Laplace, Pierre Simon de, 29, 40, 42

  Laub, Jakob, 122, 124–125, 133, 153

  Laws of thermal radiation: mathematical statement of radiation laws, 293–294; overview of radiation laws, 291–292; Planck’s law, 5, 8, 51, 74, 134, 196, 292; Planck-Wien Law, 5, 8, 9–12, 58 (see also Wien’s law this entry); Rayleigh-Jeans Law, 100, 119–120, 125, 220, 288, 291–294; Stefan-Boltzmann Law, 72–73 101; Wien’s law, 9, 11, 58, 74, 94–99, 246, 287, 292–294. See also Blackbody radiation; Thermal radiation

  Lectures on the Theory of Gases, 36

  Lenard, Philip, 79, 135, 207–208

  Light: absorption, 75–77, 270–271; Bose on quantum properties of, 219–224, 228; De Broglie’s theory on, 245–247; Einstein’s “fusion” theory of, 137; Einstein’s heuristic point of view on, 70–79; Einstein’s paper on quanta of, 67–69, 281; emission theory of, 137; and the ether, 83–85; ghost fields and, 198–199, 209–211; laws of thermodynamics and, 9–10; Maxwell’s wave theory of, 70; Nernst lamp and, 143–144; photoelectric effect, 78–79; Planck’s response to Einstein’s heuristic theory of, 80–81; Planck’s study of, 5, 6–7; stimulated emission of, 186, 224–225; spontaneous emission of, 186, 224–225; Stokes rule, 76–77; wave frequency, 75–76; wave theory of, 70, 83, 137. See also Electromagnetic (EM) radiation; Quantum theory

  Light quanta, 122, 125, 187, 217, 226, 228, 272, 279; blackbody law and, 74, 88; Bose’s method of counting, 233; De Broglie on, 245, 247, 250, 252; Einstein’s correspondence with Lorentz regarding, 134–135, 174; Einstein’s work on, 84–85, 221; force of radiation and, 139; fusion theory of, 137; ghost fields and, 209–210; photoelectric effect and, 78; Planck on, 80, 90–91, 93, 127; particulate concept of, 182, 196; pointlike energy packets of light and, 132; radiation properties and, 153–155, 192, 198; specific heat and, 106, 148; ultraviolet catastrophe and, 97, 101. See also Photons

  Linear oscillator, 174–175, 187

  Lippmann, Gabriel, 121

  Liquids, 39; Bose-Einstein condensation and, 237–238

  Lorentz, Hendrik, 14, 50, 80–81, 84, 89, 118–121, 125, 126, 158, 192; Einstein’s correspondence with, 130–135, 153–154, 167, 194, 197, 241; on ghost fields, 198; opinion of Einstein, 123–124; opinion of Einstein’s Relativity Theory, 118; on Planck’s formula, 92; on quantum theory and classical physics, 171–172, 173; Solvay Congress and, 149–150, 171–172

  Loschmidt, Josef, 38

  Lyman, Theodore, 178

  Mach, Ernst, 116, 255

  Magnetism, 30–31, 33

  Mauguin, Charles, 250

  Maric, Mileva. See Einstein, Mileva

  Maric Maric, Milos, 23

  Markwalder, Stephanie, 21–22

  Markwalder, Suzanne, 21–22

  Marsden, Ernest, 172

  Mass, 30–31, 245–246

  Massless nature of photons, 155–156, 265

  Matrix mechanics, 271–274, 280, 289; Einstein’s opinion of, 271–272; equivalence to wave mechanics, 273

  Matter, 30

  Matter waves, 265, 274–277

  Maxwell, James Clerk, 6, 12–14, 17, 45, 48–49, 51, 54, 89, 102, 104, 132, 140, 259; on atomic theory, 37–38; Einstein’s study of, 36, 84–85, 153; Faraday’s law and, 32–33; influence on Einstein, 50; on intelligent design, 42–43; on movement of molecules, 38–39; Newtonian mechanics and, 42; philosophy of science, 31–32; on Queen Victoria, 32; on Second Law of thermodynamics, 55; statistical mechanics and, 40–42; wave theory of light, 70, 83; wealth of, 165

  Maxwell-Boltzmann theory, 38

  Maxwell’s Demon, 55

  Maxwell’s equations: Boltzmann on, 33; Einstein on, 35; Lorentz on, 35; quantum theory and, 154–156, 197; Schrödinger and, 263, 265; significance of, 34–5

  McCarthy, Eugene, 227

  Metals, atomic properties of, 45

  Meyer, George, 129

  Meyer-Schmid, Anna, 129–130

  Millikan, Robert, 142, 213

  Minkowski, Hermann, 17, 19, 20, 123–124, 136

  Mittag-Leffler, Gosta, 121

  Molecules: Doppler effect, 190–191; Einstein’s hypothesis on atomic theory and, 45–46; entropy, 51–55, 74; gas, 39–41; light absorption, 75–77; movement of, 38–40; potential energy, 68–69; resonator, 91–93

  Mookerjee, Asutosh, 218

  Motion: Boltzmann’s constant and gas, 51–55; diffusion, 39; Doppler effect, 190–191; molecular, 38–40, 51–55; Newton’s laws of, 27–30, 32; periodic, 174–175 theory of relativity and, 161

  Nature, 100

  Nernst, Walther, 141–143, 272, 281; character of, 142–143; influence on Einstein, 146–148, 154, 163–165, 228; opinion on diamond experiment, 106; opinion on Einstein, 141; opinion on General Relativity, 181; Solvay and, 149–150; Third Law of thermodynamics, 144–145, 238 (see also Nernst’s Law); work of, 141–148, 157, 165, 174, 208, 228–229; World War I and, 168, 169

  Nernst lamp, 143–144
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br />   Nernst’s law, 145–146, 238

  Neutrons, 81

  Newton, Isaac, 6, 12, 13, 17, 34–35, 46, 89, 205; influence on Einstein, 35

  Newtonian mechanics, 27–30, 42, 81, 97, 106, 152, 154, 163, 200

  Newton’s First Law, 28, 60

  Newton’s Second Law, 28, 30, 32

  New York Times, 205

  Nicolai, George, 168

  Nobel prizes, 111, 113–114, 117–118, 144, 170, 195, 212–213, 252; Einstein’s nominations of Heisenberg and Schrödinger for, 280; won by Einstein, 282

  Non-linear processes with photons, 76

  Olympia Academy, 63–66, 212

  “On a Heuristic Point of View Concerning the Production and Transformation of Light,” 67

  “On Einstein’s Gas Theory,” 262

  Onnes, H. K., 149, 229

  “On the Development of Our Views concerning the Nature and Constitution of Radiation,” 136

  “On the Present Status of the Radiation Problem,” 126–127

  “On the Quantum Theorem of Sommerfeld and Epstein,” 201

  “On the Quantum Theory of Radiation,” 188

  Orbital energy, 174–178, 183–184, 200–202

  Oscillation: harmonic, 199–200, 270; Heisenberg on, 270–271; linear, 174–175, 187; Schrödinger on, 275–276

  Ostwald, Wilhelm, 113, 142

  Particles, 81, 96, 137, 284; Bose on, 221–222; de Broglie on, 247–249; energy fluctuations and, 250–251; Nernst’s heat theorem for, 228–229; principle of least action, 200

  Paschen, Friedrich, 184

  Patent office, Bern, 46–47, 62–63, 66, 122–123

  Pauli, Wolfgang, 136, 238, 255, 269, 271, 273

  Peak frequency, 95–96

  Periodic motion, 174–175

  Pernet, Jean, 18

  Perrin, Jean, 40, 142, 149, 157, 250

  Petit, Alex, 103–104

  Philosophical Magazine, 215, 218

  Photoelectric effect, 78–79, 213

  Photons, 71, 75, 155–156, 182, 193, 221–223, 230, 281; bosonic nature of, 217; de Broglie on, 245–246; gas of, 221–223, 230; ghost fields and, 276; lack of deterministic laws for, 198; massless nature of, 155–156, 265; non-linear processes with, 76; Planck on, 80, 140. See also Light quanta

  Physikalisch-Technische Reichsanstalt, 165

  Pickering, E. C., 178

  Pickering-Fowler spectrum, 178–179

  Planck, Max, 4, 67, 71, 124, 127, 146, 147, 164, 165, 192, 213, 229, 255, 272, 274, 281, 292; blackbody radiation and, 56–60; Boltzmann’s principle and, 56–58; de Broglie on, 244; Einstein’s thoughts on, 26–27, 73–74, 285; on fundamental constants, 116–117; German Physical Society and, 5, 8, 10–13; Nobel prize, 113–114; response to Einstein’s heuristic theory of light quanta, 80–81; Solvay and, 149; support for Einstein’s special theory of relativity, 88–89; as a theoretical physicist, 5–6, 13–14; on theory of relativity, 151; World War I and, 168

  Planck’s constant, 79, 111, 116–117, 154–155, 174, 200, 247; electron orbital frequencies and, 176; rest frequency and, 248

  Planck’s law, 5, 8, 51, 74, 134, 196, 292; Born’s derivation of, 219–224; Bose on, 219–224, 228; de Broglie and, 246–247; Einstein’s thoughts on, 26–27, 90–91; fluctuating force and, 191; “fusion” theory of light and, 137–138; Planck’s presentation of, 10–11, 12–13; quantum theory and, 187–189; Lord Rayleigh on, 94–99; Rayleigh-Jeans law and, 100–102; Second Law of thermodynamics and, 9–11; visible EM radiation and, 11–12

  “Planck’s Law and the Quantum Hypothesis,” 219

  Planck’s radiation law, 11–12, 113–119

  “Planck’s Theory of Radiation and the Theory of Specific Heat,” 106

  Planck-Wien Law. See Laws of thermal radiation

  Poincaré, Henri, 84, 149

  Potential energy, 68–69, 265–266

  Pressure, gas, 38, 139

  Principle of least action, 88, 200

  Probability density, 276, 282

  Protons, 81, 115–116

  Prussian Academy of Sciences, 166, 181, 213, 229, 235, 262

  Quanta of Light. See Light quanta; Photons

  Quantization of energy, 97–98, 106–110, 131–132, 281; Bohr-Sommerfeld rule, 170–174; Einstein and, 107, 200–202; Heisenberg and, 270–271; Planck and, 60–61; Schrödinger and, 263–265

  Quantum chaos theory, 202–203

  Quantum freezing, 144–145

  Quantum ideal gas, 229, 231–232, 235–238

  Quantum mechanics, 268, 281; de Broglie and, 253; determinism in, 277; Einstein’s dislike of, 1–2, 277; Nernst’s heat theorem and, 228–229; significance of, 2

  “Quantum Mechanics of Collision Phenomena,” 276

  Quantum theory, 3, 125–128, 162–163, 193, 212–213, 280–281; blackbody law and, 184–185; Bose-Einstein condensation and, 233–238; directed process in, 189–192; Einstein’s commitment to, 160–161, 183–184; Einstein’s struggles with, 153–156; ghost fields and, 198–199; ideal gas and, 226; Lorentz on, 171–172, 173; Maxwell’s equations and, 154–156; Nernst and, 147–148, 152–153, 228–229; Planck’s law and, 187–189; thermal equilibrium and, 185–186. See also Atomic theory; Quantum mechanics

  “Quantum Theory of the Monatomic Ideal Gas,” 229–230

  Radiation. See Electromagnetic (EM) radiation

  Radioactive decay, 182–183

  Radioactivity, 46

  Rathenau, Walter, 211–212

  Rayleigh, Lord, 93, 94, 104, 108, 165, 172, 292; Wien law and, 93, 94

  Rayleigh-Jeans law, 100–102, 119–120, 125, 220, 288, 291–294

  Reiche, Fritz, 136

  “Remarks on the Statistical Definition of Entropy for the Ideal Gas,” 261

  Rest frequency, 248

  Revue Philosophique, 66

  Ritz, Walter, 127

  Rome Congress of Mathematicians, 124

  Routh, E. J., 94

  Rubens, Heinrich, 5, 8, 11–12, 58, 98–99, 136, 143, 148, 164; on Einstein’s work, 208; Solvay and, 149

  Rutherford, Ernest, 114, 149, 170–173

  Rydberg, Johannes, 177

  Saha, Meghnad, 218

  Schrödinger, Erwin, 155, 238–240, 253, 254, 284; academic appointments of, 254–255; Bose statistics and, 238–240, 260–61; Born and, 274, 277; on directed matter waves, 276–277; formal education of, 257–259; Heisenberg and, 272–274; on ideal gases, 261–263; nomination for Nobel prize, 280; relationships with women, 256; research style, 259–260; wave equation, 254, 256, 263–267; on wavefunction, 275–276

  Second Law of thermodynamics, 9–11, 41, 48–49, 54–56; blackbody radiation and, 56–60; Maxwell and, 55

  Sliding mirror thought experiment, 138–139, 189

  Solids, 103–108, 145; atomic vibration and, 108–110; Bose-Einstein condensation and, 237–238

  Solovine, Maurice, 63–66, 64, 86

  Solvay, Ernest, 149–150, 156–158

  Solvay Congress of 1911, 149–152, 156–158, 169–172, 242, 244

  Sommerfeld, Arnold, 125–126, 136, 153–154, 163, 174, 199, 207, 229, 251, 255, 259; fine structures and, 183; on electron orbital frequency, 183–184; on orbital energy, 200–201; Schrödinger and, 263, 274; Solvay and, 158–159

  Specific heat, 97, 103–110, 141, 146–147

  Stark, Johannes, 135–136, 140, 174

  Statistical mechanics, 40–42, 48, 90, 259; Boltzmann’s principle and, 56–58; Einstein’s papers on, 67–69; free energy and, 49; Maxwell on, 40

  Stefan-Boltzmann law, 72–73, 101

  Stern, Otto, 3, 183

  Stimulated emission, 186–187, 224–225

  Stodola, Aurel, 166

  Stokes, George Gabriel, 76–77, 95

  Stokes rule, 76–77

  Strutt, John William. See Rayleigh, Lord

  Swiss Federal Institute of Technology (ETH), 163, 166, 167

  Tanner, Hans, 146

  Temperature, 38, 96; ideal gas law and, 235–236; quantum freezing and, 144–145

>   Thalen, Tobias, 112

  Theoretical physics, 5–6, 13–14, 61, 278; de Broglie and, 244–245; Einstein’s early work in, 26–27; Schrödinger and, 266–267

  Theory of relativity, 3–4; attacks on, 206–207; Einstein’s early thoughts on, 126–128, 161; Einstein’s fame from, 205–207; as “elementary” theory, 126–128; internal contradictions, 280; Nobel committee and, 212–213; Planck on, 151; time dilation and, 248. See also General theory of relativity

  Theory of Sound, The, 94

  Thermal energy, 67–68

  Thermal equilibrium, 7, 100–102, 140, 185–186, 189, 224, 250, 291

  “Thermal Equilibrium of the Radiation Field in the Presence of Matter,” 224

  Thermal radiation, 291, 293–294. See also Blackbody radiation; Laws of thermal radiation

  Thermodynamics, laws of, 9–11, 41; black-body radiation and, 56–60; Boltzmann’s constant and, 54–55; Einstein’s light-quanta hypothesis and, 74–75, 281; Einstein’s papers on, 48–49; Maxwell’s demons and, 55–56; Nernst and, 144–145, 238; ultraviolet catastrophe and, 72, 98–102

  Third Law of thermodynamics, 144–145, 238, 281

  Thirring, Hans, 257

  Thomson, J. J., 45, 95, 115, 118, 162, 170–172, 205

  Thomson, William. See Kelvin, Lord

  Time dilation, 248

  Transition frequencies, 270–271

  Trinity College, 94

  Uhland, Ludwig, 4

  Ultraviolet catastrophe, 72–73, 90–93, 97–102, 172, 288

  University of Bern, 123

  University of Zurich, 46, 122, 124, 130, 150

  Valiant Swabian, the, 4, 44

  Van ‘t Hoff, Jacobus Henricus, 113

  Velocity, 161

  Vibration, atomic, 104, 106–110, 178; de Broglie on, 248–250

  Victoria, Queen, 32

  Volume, gas, 38

  Von Laue, Max, 136, 208, 211

  Warburg, Emil, 164

  Waves: de Broglie and, 247–250, 252; direct matter, 276–277; as disturbances, 83, 265; matter, 265, 274–275; probability density, 276; in q-space, 275–276; Schrödinger and, 254, 256, 262–263; wave theory of light, 70, 81–85, 83, 137, 138–139

  Weber, Heinrich, 15–20, 26, 35, 46, 103–106, 152

  Weimar Republic, 206

  Weizmann, Chaim, 209

  Weyland, Paul, 206–207

  Whitehead, Alfred North, 205

  Wien, Wilhelm, 94–99, 120, 136, 149, 213, 272, 274, 292, 293. See also Planck’s law

  Wien’s law, 9, 11, 58, 74, 94–99, 246, 287, 292–294

 

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