434
We will now observe the appearances in their gradual formation, beginning from the slightest pressure.
435
On the slightest pressure the centre itself appears of a green colour. Then follow as far as the concentric circles extend, red and green rings. They are wide, accordingly, and no trace of a silver white space is to be seen between them. The green is produced by the blue of an imperfectly developed circle, mixing with the yellow of the first circle. All the remaining circles are, in this slight contact, broad; their yellow and blue edges mix together, thus producing a beautiful green. The red, however, of each circle, remains pure and untouched; hence the whole series is composed of, these two colours.
436
A somewhat stronger pressure separates the first circle by a slight interval from the imperfectly developed one: it is thus detached, and may be said to appear in a complete state. The centre is now a blue point; for the yellow of the first circle is now separated from this central point by a silver white space. From the centre of the blue a red appears, which is thus, in all cases, bounded on the outside by its blue edge. The second and third rings from the centre are quite detached. Where deviations from this order present themselves, the observer will be enabled to account for them, from what has been or remains to be stated.
437
On a stronger pressure the centre becomes yellow; this yellow is surrounded by a red and blue edge at last, the yellow also retires from the centre; the innermost circle is formed and is bounded with yellow. The whole centre itself now appears silver white, till at last, on the strongest pressure, the dark point appears, and the phenomenon, as described at first, is complete.
438
The relative size of the concentric circles and their intervals depends on the form of the glasses which are pressed together.
439
We remarked above, that the coloured centre is, in fact, an undeveloped circle. It is, however, often found, on the slightest pressure, that several undeveloped circles exist there, as it were, in the germ; these can be successively developed before the eye of the observer.
440
The regularity of these rings is owing to the form of the convex glasses, and the diameter of the coloured appearance depends on the greater or lesser section of a circle on which a lens is polished. We easily conclude from this, that by pressing plane glasses together, irregular appearances only will be produced; the colours, in fact, undulate like watered silks, and spread from the point of pressure in all directions. Yet, the phenomenon as thus exhibited is much more splendid than in the former instance, and cannot fail to strike every spectator. If we make the experiment in this mode, we shall distinctly see, as in the other case, that, on a slight pressure, the green and red waves appear; on a stronger, stripes of blue, red, and yellow, become detached. At first, the outer sides of these stripes touch; on increased pressure they are separated by a silver white space.
441
Before we proceed to a further description of this phenomenon, we may point out the most convenient mode of exhibiting it. Place a large convex glass on a table near the window; upon this glass lay a plate of well-polished mirror-glass, about the size of a playing-card, and the mere weight of the plate will press sufficiently to produce one or other of the phenomena above described. So, also, by the different weight of plates of glass, by other accidental circumstances, for instance, by slipping the plate on the side of the convex glass where the pressure cannot be so strong as in the centre, all the gradations above described can be produced in succession.
442
In order to observe the phenomenon it is necessary to look obliquely on the surface where it appears. But, above all, it is to be remarked that by stooping still more, and looking at the appearance under a more acute angle, the circles not only grow larger but other circles are developed from the centre, of which no trace is to be discovered when we look perpendicularly, even through the strongest magnifiers.
443
In order to exhibit the phenomenon in its greatest beauty, the utmost attention should be paid to the cleanness of the glasses. If the experiment is made with plate-glass adapted for mirrors, the glass should be handled with gloves. The inner surfaces, which must come in contact with the utmost nicety, may be most conveniently cleaned before the experiment, and the outer surfaces should be kept clean while the pressure is increased.
444
From what has been said it will be seen that an exact contact of two smooth surfaces is necessary. Polished glasses are best adapted for the purpose. Plates of glass exhibit the most brilliant colours when they fit closely together, and for this reason the phenomenon will increase in beauty if exhibited under an air-pump, by exhausting the air,
445
The appearance of the coloured rings may be produced in the greatest perfection by placing a convex and concave glass together which have been ground on similar segments of circles. I have never seen the effect more brilliant than with the object-glass of an achromatic telescope, in which the crown-glass and flint-glass were necessarily in the closest contact.
446
A remarkable appearance takes place when dissimilar surfaces are pressed together; for example, a polished crystal and a plate of glass. The appearance does not at all exhibit itself in large flowing waves, as in the combination of glass with glass, but it is small and angular, and, as it were, disjointed: thus it appears that the surface of the polished crystal, which consists of infinitely small sections of lamellie, does not come so uninterruptedly in contact with the glass as another glass-plate would.
447
The appearance of colour vanishes on the strongest pressure, which so intimately unites the two surfaces that they appear to make but one substance. It is this which occasions the dark centre, because the pressed lens no longer reflects any light from this point; for the very same point, when seen against the light, is perfectly clear and transparent. On relaxing the pressure, the colours, in like manner, gradually diminish, and disappear entirely when the surfaces are separated.
448
These same appearances occur in two similar cases. If entirely transparent masses become partially separated, the surfaces of their parts being still sufficiently in contact, we see the same circles and waves more or less. They may be produced in great beauty by plunging a hot mass of glass in water; the different fissures and cracks enabling us to observe the colours in various forms. Nature often exhibits the same phenomena in split rock crystals.
449
This appearance, again, frequently displays itself in the mineral world in those kinds of stone which by nature have a tendency to exfoliate. These original lamellae are, it is true, so intimately united, that stones of this kind appear altogether transparent and colourless, yet, the internal layers become separated, from various accidental causes, without altogether destroying the contact: thus the appearance, which is now familiar to us by the foregoing description, often occurs in nature, particularly in calcareous spars; the specularis, adularia, and other minerals of similar structure. Hence it shows an ignorance of the proximate causes of an appearance so often accidentally produced, to consider it so important in mineralogy, and to attach especial value to the specimens exhibiting it.
450
We have yet to speak of the very remarkable inversion of this appearance, as related by men of science. If, namely, instead of looking at the colours by a reflected light, we examine them by a transmitted light, the opposite colours are said to appear, and in a mode corresponding with that which we have before described as physiological; the colours evoking each other. Instead of blue, we should thus see red-yellow; instead of red, green, &c., and vice versa &c. We reserve experiments in detail, the rather as we have ourselves still some doubts on this point.
451
If we were now called upon to give some general explanation of these epoptical colours, as they appear under the first condition, and to show their connexion with the previously det
ailed physical phenomena, we might proceed to do so as follows: —
452
The glasses employed for the experiments are to be regarded as the utmost possible practical approach to transparence. By the intimate contact, however, occasioned by the pressure applied to them, their surfaces, we are persuaded, immediately become in a very slight degree dimmed. Within this semi-transparence the colours immediately appear, and every circle comprehends the whole scale; for when the two opposites, yellow and blue, are united by their red extremities, pure red appears: the green, on the other hand, as in prismatic experiments, when yellow and blue touch.
453
We have already repeatedly found that where colour exists at all, the whole scale is soon called into existence; a similar principle may be said to lurk in the nature of every physical phenomenon; it already follows, from the idea of polar opposition, from which an elementary unity or completeness results.
454
The fact that a colour exhibited by transmitted light is different from that displayed by reflected light, reminds us of those dioptrical colours of the first class which we found were produced precisely in the same way through semi-opacity. That here, too, a diminution of transparency exists there can scarcely be a doubt; for the adhesion of the perfectly smooth plates of glass (an adhesion so strong that they remain hanging to each other) produces a degree of union which deprives each of the two surfaces, in some degree, of its smoothness and transparence. The fullest proof may, however, be found in the fact that in the centre, where the lens is most strongly pressed on the other glass, and where a perfect union is accomplished, a complete transparence takes place, in which we no longer perceive any colour. All this may be hereafter confirmed in a recapitulation of the whole.
455
Second condition. — If after breathing on a plate of glass, the breath is merely wiped away with the finger, and if we then again immediately breathe on the glass, we see very vivid colours gliding through each other; these, as the moisture evaporates, change their place, and at last vanish altogether. If this operation is repeated, the colours are more vivid and beautiful, and remain longer than they did the first time.
456
Quickly as this appearance passes, and confused as it appears to be, I have yet remarked the following effects: — At first all the principal colours appear with their combinations; on breathing more strongly, the appearance may be perceived in some order. In this succession it may be remarked, that when the breath in evaporating becomes contracted from all sides towards the centre, the blue colour vanishes last.
457
The phenomenon appears most readily between the minute lines, which the action of passing the fingers leaves on the clear surface; a somewhat rough state of the surface of the glass is otherwise requisite. On some glass the appearance may be produced by merely breathing; in other cases the wiping with the fingers is necessary: I have even met with polished mirror-glasses, one side of which immediately showed the colours vividly; the other not. To judge from some remaining pieces, the former was originally the front of the glass, the latter the side which was covered with quicksilver.
458
These experiments may be best made in cold weather, because the glass may be more quickly and distinctly breathed upon, and the breath evaporates more suddenly. In severe frost the phenomenon may be observed on a large scale while traveling in a carriage; the glasses being well cleaned, and all closed. The breath of the persons within is very gently diffused over the glass, and immediately produces the most vivid play of colours. How far they may present a regular succession I have not been able to remark; but they appear particularly vivid when they have a dark object as a background. This alternation of colours does not, however, last long; for as soon as the breath gathers in drops, or freezes to points of ice, the appearance is at once at an end.
459
Third condition. — The two foregoing experiments of the pressure and breathing may be united; namely, by breathing on a plate of glass, and immediately after pressing the other upon it. The colours then appear as in the case of two glasses unbreathed upon, with this difference, that the moisture occasions here and there an interruption of the undulations. On pushing one glass away from the other the moisture appears iridescent as it evaporates.
460
It might, however, be asserted that this combined experiment exhibits no more than each single experiment; for it appears the colours excited by pressure disappear in proportion as the glasses are less in contact, and the moisture then evaporates with its own colours.
461
Fourth condition, — Iridescent appearances are observable in almost all bubbles; soap-bubbles are the most commonly known, and the effect in question is thus exhibited in the easiest mode; but it may be observed in wine, beer, in pure spirit, and again, especially, in the froth of chocolate.
462
As in the above cases we required an infinitely narrow space between two surfaces which are in contact, so we can consider the pellicle of the soap-bubble as an infinitely thin lamina between two elastic bodies; for the appearance in fact takes place between the air within, which distends the bubble, and the atmospheric air.
463
The bubble when first produced is colourless; then coloured stripes, like those in marble paper, begin to appear: these at length spread over the whole surface, or rather are driven round it as it is distended.
464
In a single bubble, suffered to hang from the straw or tube, the appearance of colour is difficult to observe, for the quick rotation prevents any accurate observation, and all the colours seem to mix together; yet we can perceive that the colours begin at the orifice of the tube. The solution itself may, however, be blown into carefully, so that only one bubble shall appear. This remains white (colourless) if not much agitated; but if the solution is not too watery, circles appear round the perpendicular axis of the bubble; these being near each other, are commonly composed alternately of green and red. Lastly, several bubbles may be produced together by the same means; in this case the colours appear on the sides where two bubbles have pressed each other flat.
465
The bubbles of chocolate-froth may perhaps be even more conveniently observed than those of soap; though smaller, they remain longer. In these, owing to the heat, an impulse, a movement, is produced and sustained, which appears necessary to the development and succession of the appearances.
466
If the bubble is small, or shut in between others, coloured lines chase each other over the surface, resembling marbled paper; all the colours of the scale are seen to pass through each other; the pure, the augmented, the combined, all distinctly clear and beautiful. In small bubbles the appearance lasts for a considerable time.
467
If the bubble is larger, or if it becomes by degrees detached, owing to the bursting of others near, we perceive that this impulsion and attraction of the colours has, as it were, an end in view; for on the highest point of the bubble we see a small circle appear, which is yellow in the centre; the other remaining coloured lines move constantly round this with a vermicular action.
468
In a short time the circle enlarges and sinks downwards on all sides; in the centre the yellow remains; below and on the outside it becomes red, and soon blue; below this again appears a new circle of the same series of colours: if they approximate sufficiently, a green is produced by the union of the border-colours.
469
When I could count three such leading circles, the centre was colourless, and this space became by degrees larger as the circles sank lower, till at last the bubble burst.
470
Fifth condition. — Very delicate pellicles may be formed in various ways: on these films we discover a very lively play of colours, either in the usual order, or more confusedly passing through each other. The water in which lime has been slaked soon skims over with a coloured pellicle: the same happens on the surface of stagnant wat
er, especially if impregnated with iron. The lamellae of the fine tartar which adheres to bottles, especially in red French wine, exhibit the most brilliant colours, on being exposed to the light, if carefully detached. Drops of oil on water, brandy, and other fluids, produce also similar circles and brilliant effects: but the most beautiful experiment that can be made is the following: — Let aqua fortis, not too strong, be poured into a flat saucer, and then with a brush drop on it some of the varnish used by engravers to cover certain portions during the process of biting their plates. After quick commotion there presently appears a film which spreads itself oat in circles, and immediately produces the most vivid appearances of colour.
471
Sixth condition. — When metals are heated, colours rapidly succeeding each other appear on the surface: these colours can, however, be arrested at will.
472
If a piece of polished steel is heated, it will, at a certain degree of warmth, be overspread with yellow. If taken suddenly away from the fire, this yellow remains.
As the steel becomes hotter, the yellow appears darker, intenser, and presently passes into red. This is difficult to arrest, for it hastens very quickly to bright blue.
474
This beautiful blue is to be arrested if the steel is suddenly taken out of the heat and buried in ashes. The blue steel works are produced in this way. If, again, the steel is held longer over the fire, it soon becomes a light blue, and so it remains.
475
These colours pass like a breath over the plate of steel; each seems to fly before the other, but, in reality, each successive hue is constantly developed from the preceding one.
476
If we hold a penknife in the flame of a light, a coloured stripe will appear across the blade. The portion of the stripe which was nearest to the flame is light blue; this melts into blue-red; the red is in the centre; then follow yellow-red and yellow.
Works of Johann Wolfgang von Goethe Page 312